Elastomer Tackifiers

Elastomer tackifiers are those that produce green tack in elastomers. The term “tack” refers to the ability of two uncured rubber materials to resist separation after bringing them into contact for a short time under relatively high pressure. Building tack of rubber components is an important pre-requisite to enable tyre building on the tyre building drum where different rubber layers are put together on the tyre building drum before they are cured. Another important property of tackifier is, it should retain its tack on storage. A good tackifier, therefore, should have the following properties :

 

  • Very high initial and extreme long-term tackiness
  • No adverse effect on the rubber compound cure on scorch
  • No interference on (a) rubber to metal bonding (b) rubber to fabric bonding
  • Physical properties of the cured rubber remain unchanged
  • No effect on the performance of aged rubber compound properties
  • Improves rubber compound process reliability
  • Show extreme good performance in silica / s-SBR based rubber compound.
Fig.1:  Molecular Weight DistributionCaption

 

In general, NR has enough tack because of the presence of a very high quantity of low molecular weight fraction, having its wide molecular weight distribution. Its low molecular weight fraction also generates during its break down in machines. On the contrary, synthetic rubber lack in tack property because of the absence of enough low molecular weight fraction in them, having narrow molecular weight distribute on (Fig.1). Synthetic rubber also resists in the molecular break down upon mastication and therefore, cannot produce low molecular weight fraction. Resins are typically produced with molecular weights (Mw) between 1,000 and 2,000 with maximum Mw around 3000. The molecular weight is important since tackifying resins work at the surface of the rubber compound and must be able to migrate to the surface to be effective. If the molecular weight is too low, the resin will remain soluble in the elastomer and not migrate its way to the surface. If the molecular weight is too high, the elastomer will be insoluble in the elastomer. Rubber industries use both synthetic and natural resins for tack. Following three types are in major use in the industry :

  1. Aromatic Resins (Phenolic, Cumaron Indane)
  2. Petroleum based resins
  3. Plant Resins ( wood rosin resins,Terpene resins)

Only plant resin is a source of natural resins. However, due to product consistency and different compatibility factors, synthetic resins are in major use. Besides tyre and other rubber applications, the major end-uses for resins are in pressure-sensitive adhesives, hot-melt adhesives, road markings, paints, caulks, and sealants. Manufacturers use hydrocarbon resins to produce hot melt adhesives (for infant and feminine) and packaging applications in addition to glue sticks, tapes, labels and other adhesive applications. All resins are sticky and because of their low molecular weight they migrate (diffuse) easily on the rubber product surface and behaves sticky and that causes tack. Tack property is apparently due to two major reasons :

  • Spontaneous diffusion of molecules between two uncured rubber layers.
  • Strong molecular forces resulting high degree of crystallinity

Highest level of tack in NR could be due to both the reasons, which means, NR has a high degree of crystallinity (stress induced crystallization) and it has also broad (wider) molecular weight distribution (Fig.1), so that, having plenty of lower molecular fraction can diffuse faster between two layers in contact each other. NR is reported to improve upon its tack on mastication because it generates a higher number of lower molecular weight fraction chains upon breaking down on shearing forces in machines. CR (Neoprene Rubber) shows exceptional adhesive property because it shows the highest degree of crystallinity, even much greater than NR, due to its strong intermolecular attractive force.

Honestly, NR may not require any tackifier because it has enough low molecular weight fraction of chain molecules, due to its wider molecular weight distribution (Fig.1), to be migrated on the rubber component surface and can produce enough tack. It loses its tack mostly because it might have been processed at a higher temperature and is already in the premature vulcanization stage. It can also happen due to the fact that although calendaring or extrusions were done at the right temperature stock was made before adequate cooling and thereby allowed scorching in windup liners. It also loses its tack at cold ambient temperature, in the rainy season and also if the filler level is too high or if the viscosity of the stock is substantially higher than required. However, all synthetic rubber or when synthetic rubber (SBR,BR) is blended with NR, may require to add adequate resins for compound processing.

Except C4,C5 petroleum-based resins, all other types of resins are compatible with NR and is added 1-2 phr. Comparatively C9 petroleum-based resin is better in NR.  Plant-based resins are found to work better in 100% NR. When NR is compounded with synthetic rubber, the tackifier is a must and the dose could be as high as 2-4 phr depending on the content of synthetic rubber, oil and filler in the compound matrix.  All synthetic rubber lag in rubber tack because, in general, synthetic rubber has :

  • Narrow molecular weight distribution
  • It resisting break down of molecular chains under mechanical shear
  • Synthetic rubber is in very pure form

Aromatic Resins (Phenolic, Cumaron Indane) work better in SBR and BR than plant based resins. For hydrocarbon type of elastomers like butyl , halobutyl , EPM and EPDM , petroleum base resin (C4,C5) work better and usually added with 1-2 phr in the formulation, However, with a higher dose of filler, 2-4 phr tackifier could also be added.

Tackifier resins are added to base polymers/elastomers not only  to improve tack (ability to stick) but it also helps in better wetting with filler. Increase in tensile strength by adding resins has been witnessed in different types of elastomers, aromatic resins have been witnessed to increase tensile strength of SBR and its blend.

Effect of Environment on Rubber Tack

The tack of a rubber article is greatly affected by environmental conditions such

as temperature, ozone level and humidity. Environment can not influence tack, however,  if processed rubber compound is used with in 24 hrs. High temperature and humidity conditions have a detrimental effect on the initial tack and tack retention of an elastomer. Phenolic tackifying resins can help improve tack under these conditions, but they have their limits under extreme conditions. Superior tack retention under the influence of high humidity can be often be achieved with epoxy resin modified alkylphenol-formaldehyde polymers.

Hydrocarbon based tackifying resins are sometimes used as a low-cost alternative to phenolic tackifying resins. However, hydrocarbon resins are not as effective at maintaining tack under adverse environmental conditions, like elevated temperature and high humidity, nor do they have the same tack retention. Hydrocarbon resins however, preferred in butyl and EPDM rubber compound due to their compatibility.

Hydrocarbon resins are not as efficient as phenolic tackifying resins, and higher levels are often required to achieve the same tack. High tackifier resin levels can cause a loss in tensile strength, tear strength and, most importantly, hysteresis. In applications where these properties, especially hysteresis, are important, phenolic tackifying resins are excellent choices and should be used.

 

Zeon Board Approves Higher Budget For Cyclo Olefin Polymer Facility

Zeon Board Approves Higher Budget For Cyclo Olefin Polymer Facility

Following a resolution by its Board of Directors on 29 August 2025, Zeon Corporation has formally revised the total investment for its upcoming cyclo olefin polymer (COP) production plant. The new total investment is now projected to be approximately JPY 78.0 billion (approximately USD 525.70 million), a significant increase from the initial estimate of approximately YEN 70.0 billion (approximately USD 471.77 million) announced in June 2024.

This upward revision is attributed to anticipated increases across key construction areas, including rising costs for labour, raw materials and equipment. The updated financial framework incorporates both confirmed and projected cost escalations to ensure accurate budgeting. Zeon Corporation intends to fund the entire investment through a combination of internally generated capital and loans from financial institutions.

The new facility remains on schedule for completion in the first half of fiscal year 2028. Due to this timeline, the substantial investment is not expected to materially affect the company's consolidated financial results for the fiscal year ending 31 March 2026. The project is a central pillar of the company’s medium-term business strategy, identified as a major future growth driver.

The decision to proceed with the plant underscores the strong market outlook for Zeon’s cyclo olefin polymers. These advanced materials are prized for their superior optical clarity, extremely low water absorption and high purity. While already established in applications like optical films and lenses, demand is growing rapidly from the medical and semiconductor industries. By expanding its production capacity, Zeon aims to capitalise on this robust and expanding demand, thereby strengthening its market position and enhancing its corporate value over the medium to long term.

Kraton And International Paper Finalise Agreements For Operational Continuity In Savannah

Kraton And International Paper Finalise Agreements For Operational Continuity In Savannah

In a move to ensure operational continuity, Kraton Corporation has finalised service agreements with International Paper for its Savannah, Georgia facility. As a leading global producer of specialty polymers and biobased pine chemical products, Kraton will continue to receive essential site services from International Paper, a leader in sustainable packaging. This arrangement guarantees an uninterrupted production and supply of critical pine chemicals for the global market.

The agreements solidify both companies' shared commitment to reinforcing the pine chemicals value chain and providing reliable service to their customers. For Kraton, this partnership provides stability as it makes strategic infrastructure investments at the Savannah plant. These planned upgrades are designed to facilitate the site's long-term independent operations, supporting Kraton’s broader focus on business resilience and future growth. This initiative reinforces Kraton's position as a global leader in delivering high-performance, sustainable, bio-based solutions.

Minco van Breevoort, President, Kraton Pine Chemicals, said, “Securing this agreement reinforces our unwavering commitment to our customers and the pine chemicals industry. It’s business as usual. Our teams are fully aligned to ensure reliable operations, and this agreement provides continuity of supply to pine chemical markets as we invest in our long-term capabilities.”

Chris Roeder, Vice President and General Manager, Pine Chemicals and Low Carbon Solutions, International Paper, said, “We are pleased to renew and extend our partnership with Kraton. This arrangement confirms our long-standing relationship with Kraton and our commitment to being a reliable, long-term partner to Kraton and participant in the pine chemicals markets for years to come.”

Retreading’s Stubborn Struggle

Tyre dump

Despite decades of presence and proven sustainability benefits, the global truck tyre retreading industry remains mired in perception problems and systemic inertia. As raw material costs rise and environmental pressures mount, retreading should be a no-brainer. Yet, it continues to be sidelined by outdated mindsets, customer ignorance and a lack of cohesive industry messaging. Tirecore CEO Garry Drisdelle, in a candid interview with Tyre Trends, paints a picture of a sector at risk – not because it lacks value, but because it has failed to communicate it. The stakes, he warns, are too high for complacency.

Despite decades of existence, the retreading industry still wrestles with fundamental challenges across the world – not least the stubborn perception among customers and stakeholders about the true value of retreaded truck tyres. Tirecore Chief Executive Officer Garry Drisdelle pulls no punches in diagnosing the sector’s issues and outlining the uphill battle ahead.

Speaking to Tyre Trends, he said, “Tirecore is primarily a supplier of quality truck tyre casings to the retread industry. But while retreading should logically form the cornerstone of sustainable tyre use, the industry remains far from mainstream acceptance.”

“Educating the customers really as to how much upcycling, how much can we save – it’s beyond the pennies or pounds you save on the initial purchase,” Drisdelle said. Yet, frustratingly, many customers remain fixated on upfront costs instead of the total lifecycle value of a tyre.

This fixation, he implies, represents a systemic failure within the industry. “The industry has to do a better job towards educating the consumers, which primarily are fleet owners, beyond the initial purchase,” said Drisdelle. The inability to shift consumer mindset threatens to leave retreading as a niche rather than a necessity.

Tirecore positions itself primarily as a global supplier of high-quality truck tyre casings to the retread industry, operating across markets that include the United States, Canada and India. Rather than manufacturing or retreading tyres directly, the company serves as a critical node in the circular economy of commercial tyres, ensuring that valuable casings find extended life through retreading.

“We are in the business of preserving 85 percent of the tyre components existing material’s value saving valuable resources,” said Drisdelle.

The company’s operational model is rooted in the principle of upcycling over replacement, focusing on longevity and material reuse rather than disposability. While Tirecore’s precise logistical affiliations remain unspecified, its strategic direction is clearly aimed at aligning with sustainability mandates and evolving global market demands.

DISPOSABLE TREATMENT

Drisdelle highlights a critical contradiction. Tyres are one of the most safety-critical components on the road, yet they are taken for granted at a staggering scale. “Picture a truck is rolling down the highway at 100km/h pulling 20,000 kilogrammes of freight, riding on just 6-8-10 rolling rubber contact points. Tyres are one of the most critical transportation components, yet we treat them like disposable goods. How taken for granted is that product?”

Even as raw material prices surge and truck tyre costs climb, the entrenched perception treats tyres as disposable consumables. “We need to reframe the conversation – a tyre should be seen as an asset and not a consumable,” Drisdelle emphasises.

This disconnect reveals deeper issues prevalent within the industry. Retreading has not been effectively communicated as a financial and environmental beneficial in the long tome. Moreover, legislative inconsistency and lack of incentives for the industry as a whole is a deterrent that needs to be addressed immediately.

Drisdelle insists that retreading should be the environmental rallying point for the sector. “We have 85 percent of the material in the original product that is quite capable of being reprocessed and upcycled many times,” he said.

He contrasts upcycling favourably with recycling, which he argues requires more energy and effort than the original production process, especially in plastics and other materials: “By the time you just recycle something, the energy to recycle it is more than the process.”

Yet these arguments come with an implicit critique that the industry has failed to effectively translate this environmental rationale into a compelling value proposition for customers and regulators alike.

LEGISLATIVE MOMENTUM

Drisdelle points to potential legislation requiring truck tyres to be recyclable or retreadable as a possible catalyst for change. “Picture if legislation comes out that you’re not allowed to sell truck tyres unless they’re recyclable from their ingredients unless they’re retreadable,” he noted.

However, he quickly tempers this with realism stating, “We can never get to zero. That’s a cool little marketing thing but it’s an impossibility in the world of physics and science.”

This admission highlights the gap between aspirational sustainability goals and practical realities, a gap that leaves retreading vulnerable to accusations of greenwashing or insufficient progress.

ADAPT OR STAGNATE

Looking to the future, Drisdelle’s plan is pragmatic but cautious. “Our future plans are to keep up with the market demand, to evolve as the market evolves. Pivot and prosper,” he said.

Such a measured approach reflects the uncertainty and fragmentation within the industry. The promise of retreading remains strong, but without decisive action on education, regulation and innovation, the sector risks losing ground to cheaper, new tyres or alternative technologies.

The recurring theme throughout Drisdelle’s commentary is education, or rather, the lack of it. “The education of the fleet owners is primary to everything. The education of the industry to build a better tyre is somewhat secondary,” he stated.

This stark admission speaks volumes. Despite retreading’s environmental and economic advantages, a fundamental communication failure continues to hobble the industry.

Drisdelle points out the irony stating, “Without a widespread cultural shift in perception, retreading will struggle to move beyond a cost-saving niche for price-sensitive fleets to a mainstream standard.”

Drisdelle’s blunt assessment of the retread industry reveals a sector caught between its potential and its persistent shortcomings. Tirecore’s role as a global supplier to retreaders is clear but the wider challenge remains.

Without significant progress on education and regulatory backing, the retread industry risks remaining on the margins, overshadowed by the convenience of new tyres and the pressures of market inertia.

Retreading’s promise is substantial. But, as Drisdelle’s comments underscore, fulfilling that promise demands a candid reckoning with the industry’s educational failures and a relentless push for change or face stagnation in a rapidly evolving tyre market. n

India’s Tyre Recycling Industry Enters New Era With Gujarat’s Green Light To Continuous Pyrolysis

Tyre recycling

India’s tyre recycling sector, long plagued by fragmented operations and lax compliance, is undergoing a critical overhaul. With Gujarat’s recent approval for continuous pyrolysis plants, the industry is moving decisively towards cleaner, scalable and regulation-driven solutions. This shift signals more than a technological upgrade and it’s a rebuke of outdated batch systems and a call for formalisation, traceability and environmental accountability. As global demand for sustainable materials rises, India’s pivot positions it as a potential leader in circular economy practices. In conversation with TRRAI President Chetan Joshi, we explore how this development could redefine the future of tyre waste management at home and abroad.

India’s tyre recycling sector is on the cusp of a transformational shift with the Gujarat Pollution Control Board (GPCB) approving the establishment of continuous pyrolysis plants in the state. The move marks a significant departure from traditional batch-based tyre processing systems, promising to boost efficiency, environmental compliance and resource recovery at an industrial scale.

“This shift is nothing short of revolutionary,” said President of the Tyre and Rubber Recyclers Association of India (TRRAI) Chetan Joshi. “We’re moving from outdated, fragmented batch operations to streamlined, automated continuous pyrolysis systems. This is going to uplift the entire industry, from cleaner emissions to higher resource recovery, better traceability and serious investor interest. It sets a new national standard and will accelerate formalisation, industrial-scale operations and a far more sustainable approach across India.”

The approval has been met with optimism by recyclers and environmental advocates alike as it signifies a structural change in how end-of-life tyres will be handled in India, which is home to more than 1.8 million tonnes of tyre waste annually.

The Gujarat model mandates stringent adherence to environmental standards, particularly concerning air quality and emissions. Continuous pyrolysis plants approved under the new framework are required to incorporate top-tier pollution control mechanisms.

“We see compliance not as an obligation but as a core design principle. Our plants are being built with advanced air pollution control devices (APCDs), real-time emissions monitoring and automation that ensures consistent performance. We’re aligning with both GPCB and CPCB regulations through pro-active design, third-party audits and integrating global best practices. It’s not just about meeting today’s standards but staying ahead of tomorrow’s,” said Joshi.

The approach reflects a broader shift in the recycling sector, where regulatory compliance is no longer viewed as a hurdle but as a strategic advantage and market differentiator.

Industrial scale

Under the new directive, each continuous pyrolysis facility must operate at a minimum capacity of 60 tonnes per day (TPD). This scale reflects the government’s push to industrialise tyre recycling and eliminate inefficient, informal practices.

“Scaling to 60 TPD is a serious industrial commitment and it means heavy investment in automation, utilities, safety systems and logistics. But it’s also the only way forward. India generates over 1.8 million tonnes of end-of-life tyres annually. This scale allows us to handle the problem responsibly while creating traceable and economically viable recycling ecosystems,” Joshi said.

With India’s growing automotive base, the urgency to develop sustainable, high-capacity recycling infrastructure has never been higher.

One of the key advantages of continuous pyrolysis lies in its outputs that include valuable petrochemical byproducts like pyrolysis oil, sustainable fuels and recovered carbon black (rCB). These materials are increasingly in demand across a range of industries, from rubber manufacturing to renewable energy.

“These by-products are entering a new phase of global relevance. Recovered carbon black is being adopted in rubber, plastics and even pigments. Pyro oil, when upgraded, is a viable alternative fuel. We’re actively engaging with global buyers and certifiers to standardise and integrate these outputs into international supply chains. The world is ready for sustainable alternatives and it’s up to us to deliver with consistency and quality,” averred Joshi.

India’s entry into this global supply chain positions it not just as a recycler of waste but as a producer of sustainable industrial materials.

Circular economy

TRRAI views this milestone as more than an environmental success. It’s a step towards realising India’s vision of a circular economy, where tyre waste is fully reintegrated into the production cycle.

“We aim to be more than recyclers. We want to be circular economy enablers. That means building systems where tyre waste is traceable from collection to output, where value is recovered and re-injected into the economy. We’re developing collection infrastructure, digital traceability and offtake agreements with industries globally. This is not just about waste; it’s about resource optimisation and environmental stewardship,” Joshi explained.

Such a shift could significantly reduce the country’s carbon footprint while fostering job creation and industrial growth.

Despite the enthusiasm, industry leaders acknowledge that challenges remain, particularly in terms of adoption among legacy operators and infrastructure gaps.

“The biggest challenge is inertia as many operators are still working in the unorganised sector with outdated setups. Then there’s infrastructure as a hurdle as tyre collection networks are underdeveloped in many parts of India. To overcome this, we’re advocating policy changes, investing in reverse logistics and training the workforce. Regulatory clarity and enforcement will be key and we’re working closely with industry associations and government bodies to drive this,” said Joshi.

Stakeholders believe that education, investment and enforcement will be pivotal to ensuring widespread transition to continuous pyrolysis systems.

Global trends

Globally, countries like those in Europe and North America have already adopted advanced tyre recycling technologies. But Joshi believes India has a unique opportunity to leapfrog older systems and build world-class facilities from scratch.

“Europe and North America have a head start, especially in policy frameworks and end-use applications. But India’s opportunity lies in scale and adaptability. We can leapfrog legacy systems and build efficient, tech-driven plants from the ground up. If we get the ecosystem right – collection, compliance and capital – we can set new benchmarks, not just catch up. India could become a global hub for tyre recycling technology,” he said.

The industry’s fast pace of development combined with India’s manufacturing and engineering capabilities could make the country a case study in sustainable industrial transformation.

Innovations in emission reduction

In line with global best practices, TRRAI and its partners are integrating innovations to ensure safety and minimal environmental impact.

“We’re integrating closed-loop systems, AI-driven control logic and multi-stage gas cleaning technology. Real-time emissions data will be available both internally and to regulators. Safety protocols are built into every operational layer, from material feeding to shutdown procedures. We’ve also prioritised workforce training and regular third-party safety audits. The goal is to operate with zero compromise on health or the environment,” Joshi explained.

Such innovations are crucial not only to maintaining regulatory compliance but also to building public and investor confidence.

The entry of advanced technologies is expected to catalyse foreign investment and technical collaboration.

“Our approach is partnership-driven. We’re already working with European and Australian technology providers and are in discussions with institutional investors. We see India as a platform for co-creation, where global IP meets local scale and agility. Through industry associations like TRRAI, we’re building collaborative networks to ensure knowledge sharing, investment facilitation and joint innovation,” Joshi noted.

This strategy could help India become a global innovation hub for recycling technologies applicable across other emerging markets.

The vision

Looking to the long term, the industry’s goals extend far beyond domestic waste management. TRRAI envisions exporting its model to developing nations facing similar challenges.

“Our vision is bold but simple. It is to create a fully circular, scalable and replicable tyre recycling ecosystem. India should not only solve its own tyre waste crisis but become a global model for how emerging markets can tackle resource recovery. We see this model being exported to Southeast Asia, Africa and Latin America. With continuous pyrolysis, India can move from reactive recycling to proactive resource management on a global stage,” Joshi concluded.

As Gujarat lights the way with its approval of continuous pyrolysis plants, India’s tyre recycling sector is poised to become a beacon of innovation and sustainability – one that could shape the future of global recycling practices. n