Elastomer tackifiers are those that produce green tack in elastomers. The term “tack” refers to the ability of two uncured rubber materials to resist separation after bringing them into contact for a short time under relatively high pressure. Building tack of rubber components is an important pre-requisite to enable tyre building on the tyre building drum where different rubber layers are put together on the tyre building drum before they are cured. Another important property of tackifier is, it should retain its tack on storage. A good tackifier, therefore, should have the following properties :

• Very high initial and extreme long-term tackiness
• No adverse effect on the rubber compound cure on scorch
• No interference on (a) rubber to metal bonding (b) rubber to fabric bonding
• Physical properties of the cured rubber remain unchanged
• No effect on the performance of aged rubber compound properties
• Improves rubber compound process reliability
• Show extreme good performance in silica / s-SBR based rubber compound.

In general, NR has enough tack because of the presence of a very high quantity of low molecular weight fraction, having its wide molecular weight distribution. Its low molecular weight fraction also generates during its break down in machines. On the contrary, synthetic rubber lack in tack property because of the absence of enough low molecular weight fraction in them, having narrow molecular weight distribute on (Fig.1). Synthetic rubber also resists in the molecular break down upon mastication and therefore, cannot produce low molecular weight fraction. Resins are typically produced with molecular weights (Mw) between 1,000 and 2,000 with maximum Mw around 3000. The molecular weight is important since tackifying resins work at the surface of the rubber compound and must be able to migrate to the surface to be effective. If the molecular weight is too low, the resin will remain soluble in the elastomer and not migrate its way to the surface. If the molecular weight is too high, the elastomer will be insoluble in the elastomer. Rubber industries use both synthetic and natural resins for tack. Following three types are in major use in the industry :

1. Aromatic Resins (Phenolic, Cumaron Indane)
2. Petroleum based resins
3. Plant Resins ( wood rosin resins,Terpene resins)

Only plant resin is a source of natural resins. However, due to product consistency and different compatibility factors, synthetic resins are in major use. Besides tyre and other rubber applications, the major end-uses for resins are in pressure-sensitive adhesives, hot-melt adhesives, road markings, paints, caulks, and sealants. Manufacturers use hydrocarbon resins to produce hot melt adhesives (for infant and feminine) and packaging applications in addition to glue sticks, tapes, labels and other adhesive applications. All resins are sticky and because of their low molecular weight they migrate (diffuse) easily on the rubber product surface and behaves sticky and that causes tack. Tack property is apparently due to two major reasons :

• Spontaneous diffusion of molecules between two uncured rubber layers.
• Strong molecular forces resulting high degree of crystallinity

Highest level of tack in NR could be due to both the reasons, which means, NR has a high degree of crystallinity (stress induced crystallization) and it has also broad (wider) molecular weight distribution (Fig.1), so that, having plenty of lower molecular fraction can diffuse faster between two layers in contact each other. NR is reported to improve upon its tack on mastication because it generates a higher number of lower molecular weight fraction chains upon breaking down on shearing forces in machines. CR (Neoprene Rubber) shows exceptional adhesive property because it shows the highest degree of crystallinity, even much greater than NR, due to its strong intermolecular attractive force.

Honestly, NR may not require any tackifier because it has enough low molecular weight fraction of chain molecules, due to its wider molecular weight distribution (Fig.1), to be migrated on the rubber component surface and can produce enough tack. It loses its tack mostly because it might have been processed at a higher temperature and is already in the premature vulcanization stage. It can also happen due to the fact that although calendaring or extrusions were done at the right temperature stock was made before adequate cooling and thereby allowed scorching in windup liners. It also loses its tack at cold ambient temperature, in the rainy season and also if the filler level is too high or if the viscosity of the stock is substantially higher than required. However, all synthetic rubber or when synthetic rubber (SBR,BR) is blended with NR, may require to add adequate resins for compound processing.

Except C4,C5 petroleum-based resins, all other types of resins are compatible with NR and is added 1-2 phr. Comparatively C9 petroleum-based resin is better in NR.  Plant-based resins are found to work better in 100% NR. When NR is compounded with synthetic rubber, the tackifier is a must and the dose could be as high as 2-4 phr depending on the content of synthetic rubber, oil and filler in the compound matrix.  All synthetic rubber lag in rubber tack because, in general, synthetic rubber has :

• Narrow molecular weight distribution
• It resisting break down of molecular chains under mechanical shear
• Synthetic rubber is in very pure form

Aromatic Resins (Phenolic, Cumaron Indane) work better in SBR and BR than plant based resins. For hydrocarbon type of elastomers like butyl , halobutyl , EPM and EPDM , petroleum base resin (C4,C5) work better and usually added with 1-2 phr in the formulation, However, with a higher dose of filler, 2-4 phr tackifier could also be added.

Tackifier resins are added to base polymers/elastomers not only  to improve tack (ability to stick) but it also helps in better wetting with filler. Increase in tensile strength by adding resins has been witnessed in different types of elastomers, aromatic resins have been witnessed to increase tensile strength of SBR and its blend.

Effect of Environment on Rubber Tack

The tack of a rubber article is greatly affected by environmental conditions such

as temperature, ozone level and humidity. Environment can not influence tack, however,  if processed rubber compound is used with in 24 hrs. High temperature and humidity conditions have a detrimental effect on the initial tack and tack retention of an elastomer. Phenolic tackifying resins can help improve tack under these conditions, but they have their limits under extreme conditions. Superior tack retention under the influence of high humidity can be often be achieved with epoxy resin modified alkylphenol-formaldehyde polymers.

Hydrocarbon based tackifying resins are sometimes used as a low-cost alternative to phenolic tackifying resins. However, hydrocarbon resins are not as effective at maintaining tack under adverse environmental conditions, like elevated temperature and high humidity, nor do they have the same tack retention. Hydrocarbon resins however, preferred in butyl and EPDM rubber compound due to their compatibility.

Hydrocarbon resins are not as efficient as phenolic tackifying resins, and higher levels are often required to achieve the same tack. High tackifier resin levels can cause a loss in tensile strength, tear strength and, most importantly, hysteresis. In applications where these properties, especially hysteresis, are important, phenolic tackifying resins are excellent choices and should be used.

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The global natural rubber (NR) market experienced fluctuating prices in August 2025 as supply constraints coincided with signs of improving demand, the Association of Natural Rubber Producing Countries (ANRPC) said in its latest Monthly NR Statistical Report.

The association noted that seasonal factors supported stronger consumption, particularly in China, where declining port inventories signalled healthier demand. However, heavy rainfall and labour shortages in key producing regions curtailed tapping activities, tightening supply conditions.

“Natural rubber prices experienced a fluctuating trend due to several factors, including constrained supply and improving demand,” ANRPC said. “Seasonal factors boosted consumption, particularly in China, where inventory reductions at major ports indicated improved demand. However, rainfall and labour shortages in producing regions limited tapping activities, tightening supply.”

According to updated data from member countries, global natural rubber production is projected to increase by 0.5 percent in 2025 compared with 2024, while demand is expected to grow by 1.3 percent over the same period.

The association said market sentiment had turned “increasingly optimistic” with stronger purchasing interest, driven by the traditional peak season for natural rubber, especially from the all-steel tyre and heavy-duty truck segments.

The ANRPC encouraged subscribers and stakeholders seeking more in-depth insights to refer to the full report or contact the ANRPC Secretariat for subscription details.

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India has launched an anti-dumping investigation into imports of Halo-Isobutene-Isoprene Rubber (HIIR) from China, Singapore and the United States, following a complaint from Reliance Sibur Elastomers Private Limited, the Directorate General of Trade Remedies (DGTR) said in a notification.

The domestic producer alleged that the three countries were exporting the rubber to India at unfairly low prices, causing injury to the local industry. The company has sought the imposition of anti-dumping duties on the product, which is used in tyre inner liners, hoses, seals, tank linings, conveyor belts and protective clothing.

The DGTR said there was prima facie evidence that imports had risen “significantly” and were being sold below normal value, resulting in price depression and affecting the domestic manufacturer’s capacity utilisation and profitability. The authority noted that the dumping “is causing material injury to the domestic industry”.

The investigation will cover the period from July 2024 to June 2025, with an examination of injury trends dating back to April 2021.

HIIR, also known as halobutyl rubber, is classified under the broader synthetic rubber tariff category. Reliance Sibur Elastomers is currently the only producer of the material within India.

If the investigation confirms dumping and injury, the DGTR may recommend the imposition of duties to offset the impact and “remove the injury to the domestic industry”. Interested parties have 30 days to submit data and make their representations to the authority.

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The global carbon black market is projected to grow from USD 27.88 billion in 2024 to USD 44.77 billion by 2034, expanding at a compound annual growth rate (CAGR) of 4.85 percent between 2025 and 2034, according to a new report by Towards Chemical and Materials, a research arm of Precedence Research.

The study estimates that the global market volume will rise from around 15.15 million tonnes in 2025 to 21.83 million tonnes by 2034, growing at a CAGR of 4.14 percent, driven primarily by increasing demand for tyres, automotive components and high-performance plastics.

Carbon black – a fine black powder made through the incomplete combustion of hydrocarbons – is a critical material used to reinforce rubber in tyre production and enhance strength, durability and UV resistance in plastics, coatings, and batteries.

Asia Pacific accounted for about 58 percent of global market share in 2024 and is expected to remain the largest and fastest-growing regional market, supported by expanding tyre and rubber manufacturing bases in China, India and Southeast Asia. The region’s carbon black market was valued at USD 16.95 billion in 2025 and is projected to reach USD 26 billion by 2034.

“The Asia Pacific region continues to lead both in production and consumption of carbon black, owing to its strong automotive, tyre and plastics industries,” the report noted, adding that China remains the world’s largest producer and consumer.

The furnace black segment dominated the market in 2024, accounting for about 60 percent of global industry share, due to its superior reinforcing properties in tyres and versatility in plastics and coatings. Meanwhile, the tyres and rubber products segment held a 55 percent share, reflecting the material’s indispensable role in the automotive sector.

Performance applications such as batteries, conductive polymers, and specialty coatings are emerging as key growth drivers. Demand for specialty carbon black and conductive grades is rising with the proliferation of electric vehicles, renewable energy systems, and electronics manufacturing.

Artificial intelligence (AI) is also shaping the carbon black industry, with automation and predictive analytics enhancing process efficiency, product consistency, and sustainability, the report said. AI-driven systems are enabling real-time monitoring and predictive maintenance in production plants, reducing waste and energy consumption.

Sustainability remains a key trend, with manufacturers investing in greener technologies, renewable feedstocks and recovered carbon black (rCB) from recycled tyres to meet circular economy goals. “Turning end-of-life tyres and rubber waste into recycled carbon black is opening new sustainable pathways for producers,” the study noted.

Among key players profiled in the report are Tokai Carbon Co., Ltd., Continental Carbon, Jiangsu C-Chem Co., Ltd., Himadri Speciality Chemical Ltd., Sid Richardson Carbon & Energy Company, Cancarb Limited, Philips Carbon Black Ltd., OCI Company Ltd., Columbian Chemicals Co. (Birla Carbon), Aditya Birla Group, and Raven SR, LLC.

Recent industry developments include PCBL Chemical Ltd.’s establishment of a wholly owned US subsidiary in Delaware in July 2025 to enhance supply chain localisation and strengthen its North American footprint, as well as the West Bengal government’s efforts to attract foreign investment in its carbon black industry to support the electric vehicle, tyre, and battery markets.

The report also forecasts rapid growth in North America, fuelled by clean manufacturing practices, sustainable process adoption and expansion in high-performance plastics and battery applications. Europe, meanwhile, is benefiting from stricter environmental regulations and the EU Green Deal, which are promoting eco-friendly and specialty grades.

The global carbon black market is expected to maintain steady long-term growth as manufacturers diversify into advanced applications and invest in sustainable production technologies to meet evolving industrial and environmental demands.

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Kraton Corporation, a leading global producer of speciality polymers and high-value biobased products derived from pine chemicals, has revealed a new strategic initiative for its Berre, France facility. The plan involves streamlining its polymer operations to concentrate exclusively on manufacturing USBC products, which will result in the cessation of HSBC production at that site.

This move is designed to bolster Kraton's long-term competitiveness by optimising its manufacturing footprint in reaction to a global overcapacity for HSBC. The company has formally started an information and consultation process with the local Works Councils, with a final decision expected following this mandatory period. The company has reaffirmed its commitment to supplying HSBC from its broader global network and to leveraging its worldwide presence to continue adapting to market demands.

Prakash Kolluri, President, Kraton Polymers, said, “Our aim with this plan is to strengthen Kraton’s long-term competitive position by optimising our manufacturing footprint in response to changing market dynamics associated with global overcapacity of HSBC production capability. With this step, we are preparing Kraton for a sustainable future by securing Kraton’s position as the leading global HSBC producer. Kraton is fully committed to supporting our customers through this transition with supply of HSBC products produced within our unmatched global manufacturing network. We recognise the impact of these actions, and are committed to a safe, respectful and supportive transition. The health, safety and well-being of the employees remain our top priorities.”

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